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Steam Turbine High Pressure Fluid System Upgrade Products

MSDS

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May be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200.  Standard must be consulted for specific requirements.  This information should be given to all individuals who may come in contact with this material.

N.A. = NOT APPLICABLE                            N.E. = NOT ESTABLISHED

1.0       CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

 

PRODUCT NAME (s):    GRIFLUBEÒ BIO-SYN, BIO-SYN AS, BIOSYN EHC

Product Description: Hydraulic Fluid

EMERGENCY

MANUFACTURER / SUPPLIER: The Hill & Griffith Co. TELEPHONE:  (800) 424-9300

1085 Summer StreetCall Chemtrec

Cincinnati, Ohio 45204

(513) 921-1075 Fax:        (513) 921-9180

2.0       HAZARD IDENTIFICATION

 

GHS Classification

Hazard Classification:                         Not classified for physical or health hazards under GHS

SYMBOL:                                             None

SIGNAL WORD:                                    None

Hazard Statements:                              None

 

Precautionary Statements

Prevention                   Wear protective gloves. Wear protective clothing and eye or face protection.

Wash hands thoroughly after handling. Avoid release to the environment. Contaminated work clothing should not be allowed out of the workplace. Avoid release into the environment. Do not eat, drink or smoke when using this product. Keep away from heat/sparks/open flames/hot surfaces. No Smoking. Take precautionary measures against static electricity.

Response                     IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing. If eye irritation persists, get medical attention.

IF ON SKIN (or hair): Take off contaminated clothing and wash before reuse. Wash with

plenty of soap and water. If skin irritation occurs, get medical advice / attention.

IF INHALED: Call POISON CENTER or physician if you fell unwell.

Storage                        Keep container tightly closed in a cool well-ventilated place.

Disposal                       Dispose of contents and container in accordance with all local, regional, national and

                                    international regulations.

POTENTIAL HEALTH EFFECTS

EYE CONTACT:  This product may cause minor eye irritation, but good hygienic practices can minimize these effects.

SKIN CONTACT:  Primary route of entry.  Frequent or prolonged contact may cause minor irritations to the skin or a skin rash (dermatitis).  Good hygienic practices can minimize these effects.

 

INHALATION:  Minor lung irritation could occur, but good hygienic practices can minimize these effects.  Exposure to vapors of this product could also cause dizziness due to possible generation of trace amounts of hydrogen sulfide at elevated temperatures.

 

INGESTION:  Material has a low order of acute or chronic oral toxicity.

 

Normal use of this product does not result in generation of an oil mist.  However, if an oil mist is generated, overexposure can cause minor and reversible irritation to the eyes, skin, and especially the lungs.  Proper personal protective equipment and sufficient ventilation can provide adequate protection.

 

CARCINOGENICITY:  None of the components present in this material at concentration equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen.

 

HMIS CODE:  1 – Health, 1 – Flammability, 0 – Reactivity

NFPA CODE:  1 – Health, 1 – Flammability, 0 – Reactivity

3.0       COMPOSITION / INGREDIENT INFORMATION

Ingredient                                                           CAS Number                                        Range (% by Wt.)

Vegetable Oil                                       1280732-24-2 &/or 120962-03-0                          95-100

Performance Additive Blend*                           Mixture                                                        0-5

 

*a proprietary blend which contains no components, at their current concentrations, that are GHS hazards.

4.0       FIRST-AID MEASURES

INHALATION:  Remove victim from further exposure and restore breathing.  Seek medical attention.

SKIN CONTACT/ABSORPTION:  Wash skin thoroughly with soap and water.  Remove contaminated clothing.  If irritation develops, seek medical attention.

EYE CONTACT:  Flush with large amounts of clear flowing water for at least 15 minutes. Remove contact lens, if present while rinsing. Hold eyelids apart to ensure rinsing of the entire surface of the eye and lids with water.  If irritation persists, seek medical attention.

INGESTION:  If ingested, DO NOT induce vomiting; give two glasses of water.  Guard against aspiration into the lungs.  If vomiting occurs, keep head below hips to prevent aspiration into the lungs.  Not expected to be acutely toxic.  If large amounts are swallowed, call a physician.

NOTE TO PHYSICIAN:  See above.

5.0       FIRE FIGHTING MEASURES

FLASHPOINT:  Greater than 500oF

        FLAMMABLE LIMITS                  LEL:  NE                              UELNE

        AUTOIGNITION TEMPERATURE:  NE

        FLAMMABILITY CLASSIFICATION: 

        EXTINGUISHING MEDIA:  Carbon dioxide, dry chemical, alcohol-resistant foam, sand water fog.

UNUSUAL FIRE AND EXPLOSION HAZARDS:  Avoid using water as it may spread fire by dispersing oil.  Water spray may be used to flush spills away from fire.  Use water spray to cool exposed surfaces.  Rags and waste paper containing this material or any oils may heat and burn spontaneously.  Rags soaked with any oils present a fire hazard and should always be stored in UL Listed or Factory Mutual approved, covered containers.  Improperly stored rags can create conditions that lead to oxidation.  Oxidation, under certain conditions, can lead to spontaneous combustion.

FIRE FIGHTING EQUIPMENT:  Use full turnout gear and full facepiece with self-contained breathing apparatus when fighting fires near this product.

        PRECAUTIONS:  Avoid streams of water, which may cause frothing of chemical or may cause material to disperse.

HAZARDOUS COMBUSTION PRODUCTS:  Carbon monoxide and/or carbon dioxide and potentially other toxic materials such as hydrogen sulfide may be generated.  Do not enter enclosed or confined space without proper protective equipment including respiratory protection.

HAZARDOUS POLYMERIZATION:  Will not occur.

6.0       ACCIDENTAL RELEASE MEASURES

Isolate area and limit access.  Remove source of heat, sparks, and flame.  Stop source of leak if possible to do so without hazard.  Wear appropriate respiratory protection and protective clothing.  For small spill, dike area and use solid or other inorganic absorbent, shovel into disposable container.  Hose down area and clean with detergent.  For large spill, dike area ahead of spill, ventilate closed areas before entry.  Pump material into holding container.  Clean area with detergent.  Prevent material from entering waterways.  If material does enter waterways, please contact the appropriate authorities immediately.  In the event of an uncontrolled release of this material, the user should determine if this release is reportable under applicable laws and regulations.

7.0       HANDLING AND STORAGE

HANDLING:  Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap and water.  Keep away from heat, sparks, and open flames.  Fixed equipment as well as transfer containers and equipment should be grounded to prevent accumulation of static charge. Close container after each use.  Do not pressurize, cut, weld, braze, solder, grind or drill on or near full or empty container.  Empty container retains residue (liquid and /or vapor) and may explode in the heat of fire.

STORAGE:  Always segregate materials by major hazard class.  Product should be handled and stored in accordance with industry accepted practices.  Store in properly closed containers that are well labeled.  Store in a dry, cool, well-ventilated area.  Store away from heat, open flame, strong oxidizers, or other source of ignition.  Keep containers closed when not in use.

8.0 EXPOSURE CONTROLS AND PERSONAL PROTECTION

INHALATION PROTECTION: Use NIOSH approved respirator for organic vapor for oil mists if exposure may be above the TLV.  Personal protective equipment is generally not needed.

EYE PROTECTION: Use safety glasses with side shields or goggles when transferring material to prevent material from splashing into the eye.

SKIN PROTECTION:  Neoprene, Nitrile, or PVA gloves to prevent skin contact.  Material is not considered a primary skin irritant.

ENGINEERING CONTROLS:  Local exhaust at point of generation.  Local or general exhaust required when using material at elevated temperatures, which accelerates generation of vapors. Emergency eye wash stations and safety showers should be available in the immediate vicinity of use or handling.

EXPOSURE GUIDELINES:

Ingredient                                                                CAS Number                                                    Exposure Limits

Vegetable Oil                                        1280732-24-2 & / or 120962-03-0                  5 mg/m3 (OSHA PEL TWA) for oil mist

15 mg/m3 (OSHA PEL TWA) total dust

Performance Additive Blend*                                Mixture                                           10 mg/m3 (ACGIH PEL TWA)

 

*a proprietary blend which contains no components, at their current concentrations, that are GHS hazards.

 

9.0       CHEMICAL AND PHYSICAL INFORMATION

Appearance and Odor:        Pale yellow, oily liquid

Odor:      Vegetable odor.

Odor threshold:    Not determined

pH:         Not determined

Melting/freezing Point(oF):                Not determined

Boiling Range (oF):             > 500ºF

Flash point, COC:                > 500ºF

Water solubility:  Insoluble

Evaporation Rate:               Not determined

Flammability:      Not Determined

Explosion limit lower:        Not determined

Explosion limit upper:        Not determined

Vapor pressure:    Not determined

Vapor density:     >1 (air=1)

Relative density (water=1):  0.920-0.925

Partition Coefficient, n-octanol/water:           Not determined

Decomposition Temperature:           Not determined

Viscosity:              a. Kinematic – not determined

  1. Dynamic – not determined

Density:                 Not determined

10.0    STABILITY AND REACTIVITY

Reactivity: Nonreactive under normal conditions.

STABILITY:  Stable under normal temperature and pressure.  Spontaneous combustion can occur.   See Unusual Fire and Explosion Procedures in Section 5.0.

CONDITIONS TO AVOID:  High surface area exposure to oxygen can result in polymerization and release of heat. Incompatible materials.

MATERIALS TO AVOID:  Strong oxidizers. Acids, Reducing agents, Nitric acid          

HAZARDOUS DECOMPOSITION: Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete combustion.  Thermal decomposition may produce hydrogen sulfide at elevated temperatures as well as oxides of nitrogen, phosphorous, and sulfur.

HAZARDOUS POLYMERIZATION:  Will not occur.

11.0    TOXICOLOGICAL INFORMATION

ACUTE TOXICITY DATA

EYE IRRITATION:  May cause eye or skin irritation/dryness; in high concentrations, vapors may be irritating to the respiratory system.

SKIN IRRITATION:  Causes skin irritation. Prolonged or repeated skin contact may cause drying, cracking or irritation.

DERMAL LD50:  NE

ORAL LD50:      NE

INHALATION LC50:  NE

12.0    ECOLOGICAL INFORMATION

Environmental Fate:  Not established

Environmental Toxicity:

Freshwater fish Toxicity: LC50   1-10 mg/l based on component data

Freshwater Invertebrates Toxicity:  EC50   <1 mg/l based on component data. Chronic effects expected at 10-100 mg/l based on component data.

Algal Inhibition:   EC50  1-10 mg/kg based on component data

Biodegradation:  This material is readily biodegradable

Bioaccumulation:  < 0.5% of the components bioconcentrate in aquatic organisms.

Mobility in soil:  Not determined.

13.0    DISPOSAL INFORMATION

Waste generated during application, demolition, breakage, or spillage may be hazardous waste as defined by RCRA (40 CFR Part 261).  Place waste and spillage in closed containers.  Dispose of in approved landfill in accordance with federal, state, and local regulations.  Do not pollute or allow material to enter waterways.  Conserve resources

14.0    TRANSPORTATION INFORMATION

        U.S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME:  Biodegradable Hydraulic Oil

HAZARD CLASS:  None

        IDENTIFICATION NUMBER:  None

        LABEL(S) REQUIRED:  None

        INTERNATIONAL INFORMATION:  None

15.0    REGULATORY INFORMATION

CERCLA SECTIONS 102A / 103 HAZARDOUS SUBSTANCES (40 CFR PART 302.4):  All ingredients listed on

inventory or exempted.

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 344):  Not Regulated

        SARA TITLE III SECTION 311 / 312 HAZARDOUS CATEGORIZATION (40 CFR 370): 

Hazard Categories            Immediate Hazard – No

Delayed Hazard – No

Fire Hazard – No

Pressure Hazard – No

Reactivity Hazard – No

 

SARA TITLE III SECTION 313 (40 CFR PART 372):  None Listed

               

U.S. INVENTORY (TSCA):  All ingredients listed on inventory or exempted.

OSHA HAZARD COMMUNICATION STANDARD:  Under normal conditions this material is not known to be hazardous.

 

16.0    OTHER INFORMATION

No additional information known.

This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.  As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s).  However, no warranty or representation with respect to such information is intended or given.

Date Prepared:  07/08/2015                              Supersedes: 08/14/2006                                    Print Date 07/08/2015

Prepared by:  Duane G. Wahl                           Title:  Quality / Lab Services Manager

As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.

 

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